Basic Science

Acids, Bases, and Salts: A Brief Introduction

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Acids, bases, and salts are fundamental concepts in chemistry that are vital to both scientific understanding and practical applications in daily life.

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From the sour taste of citrus fruits to the slippery feel of soap, these substances are all around us.

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Understanding their properties, behavior, and interactions helps in various fields such as medicine, agriculture, food science, and industry.

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In this article, we will explore the definitions, theories, properties, reactions, and uses of acids, bases, and salts—along with real-world examples that demonstrate their significance.

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What Are Acids, Bases, and Salts?

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Acids are substances that release hydrogen ions (H⁺) in an aqueous solution.
Bases are substances that release hydroxide ions (OH⁻) in an aqueous solution or accept hydrogen ions.
Salts are ionic compounds formed by the neutralization reaction between an acid and a base.

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These definitions may seem simple, but they evolve significantly under different scientific theories.

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Acids, Bases, and Salts: Theoretical Perspectives

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Arrhenius Theory

Acid: Produces H⁺ ions in water.
Base: Produces OH⁻ ions in water.
Limitations: Only applies to aqueous solutions.

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Bronsted-Lowry Theory

Acid: Proton donor.
Base: Proton acceptor.
Advantage: Not limited to aqueous solutions.

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Lewis Theory

Acid: Electron pair acceptor.
Base: Electron pair donor.
Broadest Scope: Applies to a wide variety of chemical reactions.

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Theory

Acid Definition

Base Definition

Applicability

Arrhenius

Releases H⁺ in water

Releases OH⁻ in water

Aqueous only

Brønsted-Lowry

Proton donor

Proton acceptor

General

Lewis

Electron pair acceptor

Electron pair donor

Broadest (non-aqueous)

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Properties of Acids and Bases

Acids

Sour taste (e.g., lemon juice, vinegar)
Turn blue litmus paper red
pH less than 7
React with metals to produce hydrogen gas
React with carbonates to release CO₂

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Examples:

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Hydrochloric acid (HCl)
Sulfuric acid (H₂SO₄)
Acetic acid (CH₃COOH)

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Bases

Bitter taste and slippery feel
Turn red litmus paper blue
pH greater than 7
React with acids in neutralization reactions
React with oils and fats (saponification)

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Examples:

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Sodium hydroxide (NaOH)
Ammonia (NH₃)
Calcium hydroxide (Ca(OH)₂)

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pH Scale and Indicators

The pH scale ranges from 0 to 14 and measures the acidity or basicity of a solution.

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pH < 7: Acidic
pH = 7: Neutral
pH > 7: Basic

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Common Indicators:

Litmus: Blue → Red (acid), Red → Blue (base)
Phenolphthalein: Colorless in acid, Pink in base
Methyl orange: Red in acid, Yellow in base

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Neutralization and Formation of Salts

Neutralization Reaction:

An acid reacts with a base to form a salt and water.

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General Equation:

Acid + Base → Salt + Water

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Types of Salts:

Normal Salts – All replaceable H⁺ ions replaced (e.g., NaCl)
Acid Salts – Partial replacement of H⁺ (e.g., NaHSO₄)
Basic Salts – Contain hydroxide groups (e.g., Mg(OH)Cl)
Double Salts – Contain more than one metal ion (e.g., alum)

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Chemical Equations and Examples

Hydrochloric Acid + Sodium Hydroxide

HCl + NaOH → NaCl + H₂O

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Sulfuric Acid + Calcium Hydroxide

H₂SO₄ + Ca(OH)₂ → CaSO₄ + 2H₂O

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Acetic Acid + Ammonia

CH₃COOH + NH₃ → CH₃COONH₄

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Real World Applications

Acids in Daily Life:

Sulfuric Acid: Used in car batteries and manufacturing fertilizers.
Hydrochloric Acid: Aids digestion in the human stomach.
Citric Acid: Present in citrus fruits and used as a preservative.

Bases in Daily Life:

Sodium Hydroxide: Used in soap production and drain cleaners.
Ammonia: Used in household cleaners and fertilizers.
Calcium Hydroxide: Used in construction (lime mortar).

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Salts in Daily Life:

Table Salt (NaCl): Essential for body functions and food seasoning.
Sodium Bicarbonate (NaHCO₃): Used in baking and as an antacid.
Potassium Nitrate (KNO₃): Used in fertilizers and explosives.

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Acids, bases, and salts are essential to both nature and modern science.

Their behaviors, dictated by theories from Arrhenius to Lewis, help us predict chemical reactions and design products in various industries.

Whether you’re brushing your teeth with a fluoride-based toothpaste (base) or preserving food with vinegar (acid), chemistry is at work.

Understanding these substances goes beyond the classroom, it empowers innovation in medicine, agriculture, manufacturing, and environmental science.

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